Ahhh, please allow me....
In my hometown Antwerp, the classic beer is Koninck, great soury amber beer. Palm is great too (amber, rounder taste).
Trappist ales: Westmalle (the dubbel from the tap is fantastic), Chimay, Orval (favorite, most bitter beer on the planet - incredible with old cheese), Rochefort, Westvleteren, Achel: can't go wrong here. I too prefer the dubbels over the Trippels (although that Rochefort 12°...

)
In Wallonia there are many small local breweries that make awesome beers, like La Chouffe or Moinette. Too many to name really.
I'm also a big fan of the Lambics (Geuze or Kriek) from the Brussels Region. My favorite are those brewed by Boon (please, NO mort subite or other sweet junk).
As a general tip, I'd steer clear from the mass-produced lagers like Stella, Jupiler or Maes. These aren't better than other 'standard' beers made elsewhere (unless we're talking about Heineken and Amstel

). If you have to drink one, I'd say Cristal (brewed by Alken) or maybe Primus (They have a decent witbier as well).
So, Gezondheid! (Cheers!)
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